Not all whey originating from traditional cheese production give sweet whey with a pH of min. 6.3. Cottage cheese, quark, Fromage Frais, Queso Fresco, Mozzarella, or similar products give whey with a pH of 4.6 due to the lactic acid precipitation of the milk. Lactic acid is very hygroscopic and thermoplastic and thus very difficult to dry. Neutralization can be necessary (to a pH of 5.2-5.5), and the following neutralizing agents can be used:
• Mg (OH)2 forms Mg-lactate, which is a 'dry' salt and preferred by the end-users, as it does not result in dark colouring of the meat of the animals, typically calves, eating the product
• Ca (OH)2 is also usable, but as the content of Ca++ is already high in the acid whey, the ani-mals may get digestive problems.
• NaOH is sometimes used, but is not recommendable, as Na-lactate is hygroscopic and ther-moplastic. Furthermore, it discolours the meat from the animals fed with the product. Acid whey from acidification by mineral acids like HCl or H
2SO
4 need not be neutralized. Special precautions should be taken though in the selection of the stainless steel used for the fabrication of the evaporator and spray dryer, as corrosion is a problem, especially due to the Cl- ions.
After the
evaporation the concentrate is
pre-crystallized before spray drying. Generally speaking, acid whey is more difficult to dry than sweet whey, and addition of 0.1-0.3 percent free-flowing agent, such as Tixosil, is recommended during the
drying operation.